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  Pacific climate reflected in Waipuna Cave drip water hydrochemistry

Nava-Fernandez, C., Hartland, A., Gázquez, F., Kwiecien, O., Marwan, N., Fox, B., Hellstrom, J., Pearson, A., Ward, B., French, A., Hodell, D. A., Immenhauser, A., Breitenbach, S. F. M. (2020): Pacific climate reflected in Waipuna Cave drip water hydrochemistry. - Hydrology and Earth System Sciences, 24, 6, 3361-3380.
https://doi.org/10.5194/hess-24-3361-2020

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 Creators:
Nava-Fernandez, Cinthya1, Author
Hartland, Adam1, Author
Gázquez, Fernando1, Author
Kwiecien, Ola1, Author
Marwan, Norbert2, Author              
Fox, Bethany1, Author
Hellstrom, John1, Author
Pearson, Andrew1, Author
Ward, Brittany1, Author
French, Amanda1, Author
Hodell, David A.1, Author
Immenhauser, Adrian1, Author
Breitenbach, Sebastian F. M.1, Author
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1External Organizations, ou_persistent22              
2Potsdam Institute for Climate Impact Research, Potsdam, ou_persistent13              

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 Abstract: Cave microclimate and geochemical monitoring is vitally important for correct interpretations of proxy time series from speleothems with regard to past climatic and environmental dynamics. We present results of a comprehensive cave-monitoring programme in Waipuna Cave in the North Island of New Zealand, a region that is strongly influenced by the Southern Westerlies and the El Niño–Southern Oscillation (ENSO). This study aims to characterise the response of the Waipuna Cave hydrological system to atmospheric circulation dynamics in the southwestern Pacific region in order to assure the quality of ongoing palaeo-environmental reconstructions from this cave. Drip water from 10 drip sites was collected at roughly monthly intervals for a period of ca. 3 years for isotopic (δ18O, δD, d-excess parameter, δ17O, and 17Oexcess) and elemental (Mg∕Ca and Sr∕Ca) analysis. The monitoring included spot measurements of drip rates and cave air CO2 concentration. Cave air temperature and drip rates were also continuously recorded by automatic loggers. These datasets were compared to surface air temperature, rainfall, and potential evaporation from nearby meteorological stations to test the degree of signal transfer and expression of surface environmental conditions in Waipuna Cave hydrochemistry. Based on the drip response dynamics to rainfall and other characteristics, we identified three types of discharge associated with hydrological routing in Waipuna Cave: (i) type 1 – diffuse flow, (ii) type 2 – fracture flow, and (iii) type 3 – combined flow. Drip water isotopes do not reflect seasonal variability but show higher values during severe drought. Drip water δ18O values are characterised by small variability and reflect the mean isotopic signature of precipitation, testifying to rapid and thorough homogenisation in the epikarst. Mg∕Ca and Sr∕Ca ratios in drip waters are predominantly controlled by prior calcite precipitation (PCP). Prior calcite precipitation is strongest during austral summer (December–February), reflecting drier conditions and a lack of effective infiltration, and is weakest during the wet austral winter (July–September). The Sr∕Ca ratio is particularly sensitive to ENSO conditions due to the interplay of congruent or incongruent host rock dissolution, which manifests itself in lower Sr∕Ca in above-average warmer and wetter (La Niña-like) conditions. Our microclimatic observations at Waipuna Cave provide a valuable baseline for the rigorous interpretation of speleothem proxy records aiming at reconstructing the past expression of Pacific climate modes.

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 Dates: 2020-07-012020-07-01
 Publication Status: Finally published
 Pages: -
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 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.5194/hess-24-3361-2020
MDB-ID: yes - 3072
PIKDOMAIN: RD4 - Complexity Science
Research topic keyword: Nonlinear Dynamics
Model / method: Nonlinear Data Analysis
Regional keyword: Oceania/Australia
Research topic keyword: Paleoclimate
Research topic keyword: Extremes
Organisational keyword: RD4 - Complexity Science
Working Group: Development of advanced time series analysis techniques
 Degree: -

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Title: Hydrology and Earth System Sciences
Source Genre: Journal, SCI, Scopus, p3, oa
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Pages: - Volume / Issue: 24 (6) Sequence Number: - Start / End Page: 3361 - 3380 Identifier: CoNE: https://publications.pik-potsdam.de/cone/journals/resource/journals208
Publisher: Copernicus